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1152310-69-4

1152310-69-4 Structure

1152310-69-4 Structure
IdentificationBack Directory
[Name]

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II)
[CAS]

1152310-69-4
[Synonyms]

C106 Dye
C106 Dye >=85% (HPLC)
cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II)
Ruthenate(2-), [[2,2′-bipyridine]-4,4′-dicarboxylato(2-)- N1,N1′][4,4′-bis[5-(hexylthio)-2-thienyl]-2,2′-bipyridine- N1,N1′]bis(thiocyanato-N)-
[Molecular Formula]

C44H43N6O4RuS6-
[MDL Number]

MFCD28118913
[MOL File]

1152310-69-4.mol
[Molecular Weight]

1013.3
Chemical PropertiesBack Directory
[form ]

powder (black)
[color ]

Black
[Melting point ]

196 °C (lit.)
[solubility ]

Acetonitrile and tert-butyl alcohol (volume ratio: 1/1)
Hazard InformationBack Directory
[Description]

Cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II), also called C106 Dye,  is a ruthenium-based organometallic complex. Because of its high-absorptioncoefficient, it is often used to fabricate of a high-efficiency dye-sensitized solar cell. The light-harvesting efficiency of the device can be improved by  selecting two sensitizers (C106 and organic D131) as co-sensitization. The complementary absorption spectra, favorable energy level alignment, and better surface coverage of the two dyes can reduce recombination and increase electron lifetime, improve Jsc and Voc[1-3]. 
[Uses]

A ruthenium dye for high-efficiency dye-sensitized solar cells

Power conversion efficiencies of 11.7-12.1% achieved in high-efficiency dye-sensitized solar cells under air-mass 1.5G simulated sunlights.
[References]

[1] High-Efficiency Dye-Sensitized Solar Cells: The Influence of Lithium Ions on Exciton Dissociation, Charge Recombination, and Surface States. DOI:10.1021/nn101384e.
[2] A selective co-sensitization approach to increase photon conversion efficiency and electron lifetime in dye-sensitized solar cells. DOI: 10.1039/c2cp42959d.
[3] Novel and Stable D–A?π–A Dyes for Efficient Solid-State Dye-Sensitized Solar Cells. DOI: 10.1021/acsomega.7b00067.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38-43
[Safety Statements ]

26
[WGK Germany ]

3
1152310-69-4 suppliers list
Company Name: Aladdin Scientific
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