ChemicalBook--->CAS DataBase List--->115262-00-5

115262-00-5

115262-00-5 Structure

115262-00-5 Structure
IdentificationBack Directory
[Name]

(chlorodifluoroMethyl)triMethylsilane
[CAS]

115262-00-5
[Synonyms]

Chlordifluormethyltrimethylsilan
(chlorodifluoroMethyl)triMethylsilane
Silane, (chlorodifluoromethyl)trimethyl-
[Molecular Formula]

C4H9ClF2Si
[MDL Number]

MFCD20486786
[MOL File]

115262-00-5.mol
[Molecular Weight]

158.65
Chemical PropertiesBack Directory
[Boiling point ]

90.0±40.0 °C(Predicted)
[density ]

1.039±0.06 g/cm3(Predicted)
[form ]

liquid
[color ]

colorless
Safety DataBack Directory
[Symbol(GHS) ]


GHS02
[Signal word ]

Danger
[Hazard statements ]

H225
[Precautionary statements ]

P210
[Risk Statements ]

11
[Safety Statements ]

24/25
[TSCA ]

No
[HS Code ]

29319090
Hazard InformationBack Directory
[Uses]

(Chlorodifluoromethyl)trimethylsilane, is one of the partially fluorinated compounds, which are often used for diverse applications in materials science, agrochemistry, and the pharmaceutical industry.
[Reactions]

(1) Difluoromethylenation of alkenes.

Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(2) Difluoromethylenation of alkynes.

Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(3) Difluoromethylenation of TMSCN.
Difluoromethylenation of TMSCN
Ref. J. Org. Chem. 2012, 77, 5850?5855.
(4) Difluoromethylenation of benzyl and alkylzinc halides.
Difluoromethylenation of benzyl and alkylzinc halides
Ref. Org. Lett. 2013, 15, 917 – 919.
(5) Fluorination aminocarbonylation of aldehydes
(chlorodifluoroMethyl)triMethylsilane
Ref. Angew. Chem. Int. Ed. 2022, e202115467

[References]

[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899
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