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122296-00-8

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122296-00-8 Structure

122296-00-8 Structure
IdentificationBack Directory
[Name]

1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE&
[CAS]

122296-00-8
[Synonyms]

benzotriazol-1-ylmethyl(trimethyl)silane
1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE 99%
1H-Benzotriazole, 1-[(trimethylsilyl)methyl]-
1-[(Trimethylsilyl)Methyl]-1H-1,2,3-Benzotriazole
1-((Trimethylsilyl)methyl)-1H-benzo[d][1,2,3]triazole
[Molecular Formula]

C10H15N3Si
[MDL Number]

MFCD00956443
[MOL File]

122296-00-8.mol
[Molecular Weight]

205.33
Chemical PropertiesBack Directory
[Melting point ]

56-60 °C(lit.)
[solubility ]

Well soluble in most organic solvents.
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

22-36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Hazard InformationBack Directory
[Physical properties]

mp 55–56 °C.
[Uses]

New Benzotriazole Reagents

Reactant for:
  • Alkylation reactions
  • Preparation of inhibitor of p53-MDM2 complex formation

  • Used as a one-carbon synthon for one-carbon homologation of carboxylic acids
[Uses]

1-[(Trimethylsilyl)methyl]- 1H-benzotriazole is a reagent in the preparation of ketones, carboxylic acids,One-carbon Homologation of Carboxylic Acids,Synthesis of Fused Heterocycles and fused heterocycles.
[Preparation]

1-[(trimethylsilyl)methyl]-1H-benzotriazole is readily prepared in a reaction of sodium benzotriazolide with chloromethyltrimethylsilane.
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