| Identification | Back Directory | [Name]
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE | [CAS]
129648-07-3 | [Synonyms]
(R,R)-ME-BPE
Bisdimethylphospholanoethane
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
(+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%
1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ethane, 97+%
(+)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)ethane (R,R)-Me-BPE
(+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane, Kanata purity
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE
(+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane, 97% (R,R-Me-BPE) | [Molecular Formula]
C14H28P2 | [MDL Number]
MFCD01073770 | [MOL File]
129648-07-3.mol | [Molecular Weight]
258.32 |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless oily liquid | [alpha ]
+263° ±3° (c 1, hexane) | [Boiling point ]
64-67 °C 0.06 mm Hg
| [density ]
0.940 g/mL at 25 °C
| [refractive index ]
n20/D 1.534
| [form ]
liquid | [color ]
colorless to pale-yellow | [Sensitive ]
Air Sensitive |
| Questions And Answer | Back Directory | [Reactions]
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
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