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13084-70-3

13084-70-3 Structure

13084-70-3 Structure
IdentificationBack Directory
[Name]

(20S)-3α-Amino-20-hydroxypregn-5-en-18-oic acid γ-lactone
[CAS]

13084-70-3
[Synonyms]

Gitingensine
(20S)-3α-Amino-20-hydroxypregn-5-en-18-oic acid γ-lactone
Pregn-5-en-18-oic acid, 3-amino-20-hydroxy-, γ-lactone, (3α,20S)-
[Molecular Formula]

C21H31NO2
[MOL File]

13084-70-3.mol
[Molecular Weight]

329.48
Chemical PropertiesBack Directory
[Melting point ]

160°C
Hazard InformationBack Directory
[Description]

Gitingensine is a steroidal alkaloid which occurs in Kibatalia gitingensis, being found mainly in the leaves. It is optically active with a specific rotation of [α]31D - 65° (CHCI3). The hydrochloride has m.p. 281°C; [α]23D - 59.8° (CHCI3) and is more readily obtainable in the pure form than the free base. Deamination of the alkaloid by diazotization gives the deamino derivative, m.p. 235°C. The amino group may be methylated to yield the N-methyl compound, m.p. 223-4°C but the base cannot be methylated further.
[Definition]

ChEBI: Gitingensine is a steroid. It has a role as a metabolite.
[References]

Anguilar-Santos, Philipp. J. Sci., 94, 217 (1965)
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