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1313012-94-0

1313012-94-0 Structure

1313012-94-0 Structure
IdentificationBack Directory
[Name]

1',4-Bis(t-butyl)-1,2-bis(diphenylphosphino)-3'-(di-i-propylphosphino)ferrocene, 98% HiersoPHOS-1
[CAS]

1313012-94-0
[Synonyms]

1',4-Bis(t-butyl)-1,2-bis(diphenylphosphino)-3'-(di-i-propylphosphino)ferrocene, 98% HiersoPHOS-1
[Molecular Formula]

C48H57FeP3
[MDL Number]

MFCD22666036
Chemical PropertiesBack Directory
[form ]

crystal
[color ]

orange
Questions And AnswerBack Directory
[Reaction]

  1. Direct Arylation of Heteroaromatics with Congested, Functionalised Aryl Bromides at Low Palladium Loading (0.05-0.5 mol%): furans, thiophenes, thiazoles, pyrroles functionalized with alkyl, nitrile, aldehyde, keto, and ester groups coupling with ortho-and di-ortho-substituted aryl bromides (phenyl, naphtyl, anthracenyl) bearing alkyl, aryl, alcohol, nitrile, carbonitrile, and ethoxy groups.
  2. Etherification of Functionalized Phenols with Chloroheteroarenes at Low Palladium Loading (0.2-0.5 mol%): para-, metaand ortho- mono and di-substituted phenols (bearing methyl, isopropyl, methoxy, fluoro, amino, and ester groups) coupling with chloro-pyridines, -quinolines, -hydroxypyridines, -pyrimidines, -thiazoles bearing electron-withdrawing or - donating cyano and methoxy groups.
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