ChemicalBook--->CAS DataBase List--->13466-21-2

13466-21-2

13466-21-2 Structure

13466-21-2 Structure
IdentificationBack Directory
[Name]

BARIUM PYROPHOSPHATE
[CAS]

13466-21-2
[Synonyms]

dibarium diphosphate
BARIUM PYROPHOSPHATE
Dibarium pyrophosphate
BARIUM PHOSPHATE (PYRO)
barium(2+),phosphonato phosphate
Barium pyrophosphate powder, -200 mesh, 99.9% trace metals basis
[EINECS(EC#)]

236-716-7
[Molecular Formula]

Ba2O7P2
[MDL Number]

MFCD00049850
[MOL File]

13466-21-2.mol
[Molecular Weight]

448.6
Chemical PropertiesBack Directory
[Appearance]

White powder. Soluble in acids and ammonium salts; very slightly soluble in water.
[density ]

3.900
[solubility ]

soluble in acid solutions
[form ]

white powder
[color ]

white
[Water Solubility ]

0.01 g/100mL H2O; soluble acids, NH4 salts [CRC10] [HAW93]
[Solubility Product Constant (Ksp)]

pKsp: 10.5
[CAS DataBase Reference]

13466-21-2
[EPA Substance Registry System]

Diphosphoric acid, barium salt (1:2) (13466-21-2)
Hazard InformationBack Directory
[Chemical Properties]

White powder. Soluble in acids and ammonium salts; very slightly soluble in water.
[Description]

Barium pyrophosphate has the molecular formula of Ba2P2O7 and the molecular weight of 448.5973 g/mol. It has the CAS number of 13466-21-2 and may be prepared by the solid-state reaction of the dibasic orthophosphate, or alternately by the precipitation of a soluble Ba salt with aqueous pyrophosphoric acid:
2Ba HPO4 + heat ? Ba2P2O7 +H2O
BaCl2 (aq) +H4P2O7 (aq) ? Ba2P2O7 (s) + 2HCl (aq)
The solution method produces a dihydrate, Ba2P2O7·2H2O.
[Uses]

Ba2P2O7 is a promising phosphor host material, showing different emission properties upon doping with rare earth and other elements. Bi doped Ba2P2O7 crystals exhibit broadband NIR photoluminescence.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/22
[Safety Statements ]

28
[RIDADR ]

UN 1564 6.1 / PGIII
[WGK Germany ]

3
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