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1360823-43-3

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1360823-43-3 Structure

1360823-43-3 Structure
IdentificationBack Directory
[Name]

(+)-1,13-Bis(diphenyl)phosphino-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97% (R,R,R)-(+)-Ph-SKP
[CAS]

1360823-43-3
[Synonyms]

(R,R,R)-(+)-Ph-SKP
(+)-1,13-Bis(diphenyl)phosphino-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97%
1,1'-[(5aR,8aR,14aR)-5a,6,7,8, 8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene-1,13-diyl]bis[1,1-diphenyl-Phosphine
Phosphine, 1,1'-[(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene-1,13-diyl]bis[1,1-diphenyl-
(+)-1,13-Bis(diphenyl)phosphino-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97% (R,R,R)-(+)-Ph-SKP
[Molecular Formula]

C44H38O2P2
[MDL Number]

MFCD25372932
Chemical PropertiesBack Directory
[Melting point ]

101-103°C
[alpha ]

+113° (c 1.00, CHCl3)
[form ]

solid
[color ]

white
[Sensitive ]

air sensitive
Questions And AnswerBack Directory
[Reaction]

  1. Efficient ligand for the Au(I)-catalyzed, highly stereoselective, olefin cyclopropanation of diazooxindoles.
  2. Palladium-catalyzed asymmetric allylic amination of Morita-Baylis-Hillman adducts. Exceptionally high efficiency and new mechanism.
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