ChemicalBook--->CAS DataBase List--->136779-26-5

136779-26-5

136779-26-5 Structure

136779-26-5 Structure
IdentificationBack Directory
[Name]

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
[CAS]

136779-26-5
[Synonyms]

(S,S)-ME-BPE
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
1,2-Bis[(2S,5S)-2,5-diMethyl-1-phospholanyl]ethane, 97+%
(-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane (S,S)-Me-BPE
(-)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane, Kanata purity
(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane,98+%(S,S)-Me-BPE
(-)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane, 97% (S,S-Me-BPE)
[Molecular Formula]

C14H28P2
[MDL Number]

MFCD01073771
[MOL File]

136779-26-5.mol
[Molecular Weight]

258.32
Chemical PropertiesBack Directory
[alpha ]

-263° ±3° (c 1, hexane)
[Boiling point ]

64-67 °C0.06 mm Hg
[density ]

0.938 g/mL at 25 °C
[refractive index ]

n20/D 1.535
[form ]

liquid
[color ]

colorless to pale-yellow
[Sensitive ]

Air Sensitive
Safety DataBack Directory
[Hazard Codes ]

F
[Risk Statements ]

11-17
[Safety Statements ]

24/25
[RIDADR ]

UN 2845 4.2/PG 1
[WGK Germany ]

3
[HazardClass ]

4.2
[HS Code ]

29310099
Questions And AnswerBack Directory
[Reaction]

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 136779-26-5
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