Identification | Back Directory | [Name]
2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) | [CAS]
139220-25-0 | [Synonyms]
SCHROCK'S CATALYST 2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENEB& 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM(VI)BIS(HEXAFLUORO-T-BUTOXIDE) 2,6-diisopropylphenylimido neophylidenemolybdenum(Ⅵ)bis(hexafluoro-t-butoxide) 2,6-Diisopropylphenylimidoneophylidenemolybdenum(VI)bis(hexafluorotert-butoxide) 2,6-Diisopropylphenylimidoneophylidenemolybdenum(VI)bis(hexafluoro-t-butoxide)SCHROCK'SCATALYST 1,1,1,3,3,3-Hexafluoro-2-methyl-2-propanol - [(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum (2:1) | [Molecular Formula]
C30H35F12MoNO2 | [MDL Number]
MFCD00269857 | [MOL File]
139220-25-0.mol | [Molecular Weight]
765.53 |
Questions And Answer | Back Directory | [Reaction]
- Unlike Mo(C10H12)(C12H17N)(OC4H9)2, the bis(hexafluoro-t-butoxide) (MoF6) derivative will metathesize many ordinary olefins, especially terminal olefins, and will ROMP many norbornene or substituted norbornadiene monomers to give all cis, and often isotactic, polymers.
- Useful for the "ring-closing" of dienes or the coupling of terminal olefins.
- Useful for cross-metathesis of alphatic alkenes with 2-vinyl aromatics.
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