ChemicalBook--->CAS DataBase List--->142962-95-6

142962-95-6

142962-95-6 Structure

142962-95-6 Structure
IdentificationBack Directory
[Name]

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
[CAS]

142962-95-6
[Synonyms]

(S)-Ru(OAc)2(H8-BINAP)
Ru(OAc)2[(S)-H8-binap]
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
Diacetato[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II)
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II),95%
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]rutheniuM(II) Ru(OAc)2[(S)-H8-binap]
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]
[Molecular Formula]

C44H40P2.C4H6O4Ru
[MDL Number]

MFCD09753023
[MOL File]

142962-95-6.mol
[Molecular Weight]

849.905
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[solubility ]

Chloroform
[form ]

solid
[color ]

yellow to dark brown
[Sensitive ]

air sensitive
[CAS DataBase Reference]

142962-95-6
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37
[Safety Statements ]

26
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
  2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
Reactions of 142962-95-6
Hazard InformationBack Directory
[Uses]

(S)-Ru(OAc)2(H8-BINAP) is a reagent used in the synthesis of optically active carboxylic acids.
142962-95-6 suppliers list
Company Name: career henan chemical co
Tel: +86-0371-86658258 +8613203830695 , +8613203830695
Website: www.coreychem.com/
Company Name: Chongqing Chemdad Co., Ltd
Tel: +86-023-6139-8061 +86-86-13650506873 , +86-86-13650506873
Website: http://www.chemdad.com/
Company Name: changzhou huayang technology co., ltd
Tel: +8615250961469 , +8615250961469
Website: http://www.huayangchem.com/template/eabout.html
Company Name: Alfa Chemistry
Tel: +1-5166625404
Website: https://www.alfa-chemistry.com/
Company Name: J & K SCIENTIFIC LTD.  
Tel: 010-82848833 400-666-7788
Website: http://www.jkchemical.com
Company Name: Shanghai Incat Chemtech Co.,Ltd.  
Tel: 021-57603038 13601791340
Website: http://www.incatchem.com
Company Name: Sigma-Aldrich  
Tel: 021-61415566 800-8193336
Website: https://www.sigmaaldrich.cn
Company Name: Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.  
Tel: 0371-0371-65511006 18625597674
Website: http://www.kingorgchem.com/
Company Name: LaaJoo  
Tel: 021-60702684 18516024827
Website: https://www.chemicalbook.com/ShowSupplierProductsList20079/0.htm
Company Name: Shandong Ono Chemical Co., Ltd.  
Tel: 0539-6362799 20)
Website: www.onochem.com
Company Name: Aikon International Limited  
Tel: 025-58859352 18068836627
Website: http://www.aikonchem.com
Company Name: Shenzhen Polymeri Biochemical Technology Co., Ltd.  
Tel: +86-400-002-6226 13028896684
Website: https://www.rrkchem.com
Company Name: Henan Weituxi Chemical Technology Co., Ltd.  
Tel: 0371-63284658 18135795563
Website: https://www.chemicalbook.com/supplier/15004346/
Company Name: Shanghai Haohong Pharmaceutical Co., Ltd.  
Tel: 4008210725 4008210725
Website: https://www.leyan.com/
Company Name: Beijing Jin Ming Biotechnology Co., Ltd.  
Tel: 010-60605840
Website: www.jm-bio.com/
Company Name: Henan Runfeng Catalyst Co. LTD  
Tel: 15560227177
Website: www.runcatalysts.cn/
Company Name: Shaanxi DIDU pharmaceutical and Chemical Co., Ltd  
Tel: 15229059051
Website: http://www.dideu.cn
Company Name: Pushan Industry (Shaanxi) Co., Ltd.  
Tel: 029-81310890 13571859809
Website: https://www.pushanshiye.com
Tags:142962-95-6 Related Product Information