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145060-63-5

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145060-63-5 Structure

145060-63-5 Structure
IdentificationBack Directory
[Name]

1-ETHYLPIPERIDINE HYPOPHOSPHITE
[CAS]

145060-63-5
[Synonyms]

1-ETHYLPIPERIDINE HYPOPHOSPHITE
1-Ethylpiperidinium phosphinate
1-Ethyl piperidinehypophosphite,95%
1-Ethylpiperidine hypophosphite 95%
[Molecular Formula]

C7H18NO2P
[MDL Number]

MFCD00216621
[MOL File]

145060-63-5.mol
[Molecular Weight]

179.2
Chemical PropertiesBack Directory
[Melting point ]

40-43 °C (lit.)
[Fp ]

133 °F
[storage temp. ]

2-8°C
Safety DataBack Directory
[Symbol(GHS) ]


GHS02,GHS07
[Signal word ]

Warning
[Hazard statements ]

H228-H302+H312+H332-H315-H319-H335
[Precautionary statements ]

P210-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

26-36
[RIDADR ]

UN 1325 4.1/PG 2
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Reagent for:
Synthesis of spiroketals via intramolecular iodoetherification
A facile radical cyclization diverted to a rearrangement-cyclization with base
Radical deoxygenation
Synthesis of allylic H-phosphinates
[General Description]

1-Ethylpiperidine hypophosphite promotes the carbon-carbon bond forming radical reactions in both aqueous and organic media. EPHP plays an important role of a good chain carrier during the radical addition of gem-dihalocompounds to electron-deficient olefins. It has been reported as a suitable radical reducing agent for organic halides.
Spectrum DetailBack Directory
[Spectrum Detail]

1-ETHYLPIPERIDINE HYPOPHOSPHITE(145060-63-5)IR
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