| Identification | Back Directory | [Name]
1,2-PHENYLENE PHOSPHOROCHLORIDATE | [CAS]
1499-17-8 | [Synonyms]
o-Phenylene chlorophosphate
1,2-PHENYLENE CHLOROPHOSPHATE
o-Phenylenephosphorochloridate
1,2-PHENYLENE PHOSPHOROCHLORIDATE
Catechol cyclophosphorochloridate
O,O-(o-Phenylene) chlorophosphate
2-Chloro-2-oxo-1,3,2-benzodioxaphosphole
3,2-benzodioxaphosphole,2-chloro-2-oxide
1,2-PHENYLENE PHOSPHOROCHLORIDATE, TECH.
2-Chloro-1,3-dioxa-2-phosphaindan 2-oxide
2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE 2-OXIDE
1,3,2-Benzodioxaphosphole, 2-chloro-, 2-oxide
2-Chlorobenzo[d][1,3,2]dioxaphosphole 2-oxide
o-Phenylene phosphorochloridate technical grade
8-chloro-7,9-dioxa-8$l^{5}-phosphabicyclo[4.3.0]nona-1,3,5-triene 8-oxide
2-Chloro-1,3,2-benzodioxaphosphole 2-oxide, o-Phenylene chlorophosphate | [EINECS(EC#)]
216-106-7 | [Molecular Formula]
C6H4ClO3P | [MDL Number]
MFCD00005854 | [MOL File]
1499-17-8.mol | [Molecular Weight]
190.52 |
| Hazard Information | Back Directory | [Uses]
Reactant for preparation of:
- Uridine diphosphate-glucose derivatives as potential chain terminators of β-glucan biosynthesis with antifungal activity
- Vinyloxy phosphorus monomers
| [Application]
1,2-Phenylene phosphorochloridate can be used for the phosphorylation of alcohols; peptide synthesis, β-lactam synthesis. | [Preparation]
1,2-Phenylene phosphorochloridate is prepared by heating 2,2,2-trichloro-1,3,2-benzodioxaphosphole with a slight excess of acetic anhydride. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling | [Purification Methods]
After distilling it in a vacuum, it sets to a colourless solid. It is soluble in pet ether, *benzene and slightly soluble in Et2O. [Khwaja et al. J Chem Soc (C) 2092 1970, Anschütz & Broeker Justus Liebigs Ann Chem 454 109 1927, Beilstein 6 IV 5602.] |
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