Identification | Back Directory | [Name]
Tetrakis(acetonitrile)copper(I) tetrafluoroborate | [CAS]
15418-29-8 | [Synonyms]
Cu(MeCN)4BF4 e)copper(I) TetrafL Tetrakis(acetonitriL Tetra(acetonitrile)copper(1+) tetraflu Tetra(acetonitrile)copper(1+) tetrafluoroborate Copper(I) tetra(acetonitrile) tetrafluoroborate TETRAKIS(ACETONITRILE)COPPER(1)TETRAFLUORO BORATE Copper(1+) tetrafluoroborate acetonitrile (1:1:4) Tetrakis(acetonitrile)copper(I) tetrafluoroborate Tetrakis(acetonitrile)copper(I) tetrafluoroborate 97% Copper(1+), tetrakis(acetonitrile)-, (T-4)-, tetrafluoroborate(1-) Tetrakis(acetonitrile)copper(I) tetrafluoroborate ISO 9001:2015 REACH | [Molecular Formula]
C8H12BCuF4N4 | [MDL Number]
MFCD09265110 | [MOL File]
15418-29-8.mol | [Molecular Weight]
314.558 |
Chemical Properties | Back Directory | [Melting point ]
164 °C(dec.) | [density ]
1.466 g cm-3 | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
soluble in toluene, CH2Cl2, MeCN. | [form ]
powder to crystal | [color ]
White to Almost white | [Decomposition ]
270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition) |
Hazard Information | Back Directory | [Chemical Properties]
White crystalline powder | [Uses]
Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction. | [General Description]
This product has been enhanced for catalytic efficiency. | [reaction suitability]
core: copper reagent type: catalyst | [Synthesis]
The Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.
| [Precautions]
Irritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.
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Company Name: |
Energy Chemical
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021-021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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