15418-29-8

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15418-29-8 Structure

Identification	Back Directory
[Name] Tetrakis(acetonitrile)copper(I) tetrafluoroborate
[CAS] 15418-29-8
[Synonyms] Cu(MeCN)4BF4 e)copper(I) TetrafL Tetrakis(acetonitriL Tetra(acetonitrile)copper(1+) tetraflu Tetra(acetonitrile)copper(1+) tetrafluoroborate Copper(I) tetra(acetonitrile) tetrafluoroborate TETRAKIS(ACETONITRILE)COPPER(1)TETRAFLUORO BORATE Copper(1+) tetrafluoroborate acetonitrile (1:1:4) Tetrakis(acetonitrile)copper(I) tetrafluoroborate Tetrakis(acetonitrile)copper(I) tetrafluoroborate 97% Copper(1+), tetrakis(acetonitrile)-, (T-4)-, tetrafluoroborate(1-) Tetrakis(acetonitrile)copper(I) tetrafluoroborate ISO 9001：2015 REACH
[Molecular Formula] C8H12BCuF4N4
[MDL Number] MFCD09265110
[MOL File] 15418-29-8.mol
[Molecular Weight] 314.558

Chemical Properties	Back Directory
[Melting point ] 164 °C(dec.)
[density ] 1.466 g cm-3
[storage temp. ] Inert atmosphere,Room Temperature
[solubility ] soluble in toluene, CH2Cl2, MeCN.
[form ] powder to crystal
[color ] White to Almost white
[Decomposition ] 270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition)

Hazard Information	Back Directory
[Chemical Properties] White crystalline powder
[Uses] Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.
[General Description] This product has been enhanced for catalytic efficiency.
[reaction suitability] core: copper reagent type: catalyst
[Synthesis] The Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.
[Precautions] Irritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.

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