ChemicalBook--->CAS DataBase List--->15418-29-8

15418-29-8

15418-29-8 Structure

15418-29-8 Structure
IdentificationBack Directory
[Name]

Tetrakis(acetonitrile)copper(I) tetrafluoroborate
[CAS]

15418-29-8
[Synonyms]

Cu(MeCN)4BF4
e)copper(I) TetrafL
Tetrakis(acetonitriL
Tetra(acetonitrile)copper(1+) tetraflu
Tetra(acetonitrile)copper(1+) tetrafluoroborate
Copper(I) tetra(acetonitrile) tetrafluoroborate
TETRAKIS(ACETONITRILE)COPPER(1)TETRAFLUORO BORATE
Copper(1+) tetrafluoroborate acetonitrile (1:1:4)
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Tetrakis(acetonitrile)copper(I) tetrafluoroborate 97%
Copper(1+), tetrakis(acetonitrile)-, (T-4)-, tetrafluoroborate(1-)
Tetrakis(acetonitrile)copper(I) tetrafluoroborate ISO 9001:2015 REACH
[Molecular Formula]

C8H12BCuF4N4
[MDL Number]

MFCD09265110
[MOL File]

15418-29-8.mol
[Molecular Weight]

314.558
Chemical PropertiesBack Directory
[Melting point ]

164 °C(dec.)
[density ]

1.466 g cm-3
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

soluble in toluene, CH2Cl2, MeCN.
[form ]

powder to crystal
[color ]

White to Almost white
[Decomposition ]

270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 1759 8/PG 2
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29269090
Hazard InformationBack Directory
[Chemical Properties]

White crystalline powder
[Uses]

Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.
[General Description]

This product has been enhanced for catalytic efficiency.
[reaction suitability]

core: copper
reagent type: catalyst
[Synthesis]

The Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.
[Precautions]

Irritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.
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