Identification | Back Directory | [Name]
IRON DODECACARBONYL | [CAS]
17685-52-8 | [Synonyms]
Fe3(CO)12 IRON DODECARBONYL IRON DODECACARBONYL Triiron dodecarbonyl DODECACARBONYLTRIIRON TRIIRON DODECACARBONYL TRIIRON(0) DODECACARBONYL stabilisedwith5-10%methanol Triiron dodecacarbonyl,99%,stabilized Triiron dodecacarbonyl, stabilized, 99% Triiron dodecacarbonyl, stabilized, 99% 5GR di-mu-carbonyldecacarbonyl-triangulo-triiron Iron, di-mu-carbonyldecacarbonyltri-, triangulo Iron dodecacarbonyl(Stabilized with 5-10% methanol) Triirondodecacarbonyl contains 1-10% methyl alcohol TRI-IRONDODECACARBONYL MOISTENED WITH ME THANOL(CH3OH 5-10% TRIIRON DODECACARBONYL, PROTECTED WITH 5 -10% METHYL ALCOHOL Dodecacarbonyltriiron, 96% (dry wt.), stab. with 5-10% methanol Dodecacarbonyltriiron, 95+% (Assay on dry basis), stab. with 5-10% methanol Dodecacarbonyltriiron, 96% dry weight, may contain varying amounts of methanol | [EINECS(EC#)]
241-668-5 | [Molecular Formula]
C12Fe3O12 | [MDL Number]
MFCD00135617 | [MOL File]
17685-52-8.mol | [Molecular Weight]
503.66 |
Chemical Properties | Back Directory | [Appearance]
black powder or crystals | [Melting point ]
165 °C (dec.)(lit.)
| [density ]
1.99
| [Fp ]
9℃ | [storage temp. ]
2-8°C
| [form ]
crystal | [color ]
black | [Specific Gravity]
2 | [Water Solubility ]
Insoluble in water. Soluble in non polar organic solvents. | [Sensitive ]
Air Sensitive | [Exposure limits]
ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 | [NIST Chemistry Reference]
Triiron dodecacarbonyl(17685-52-8) |
Hazard Information | Back Directory | [Chemical Properties]
black powder or crystals | [Uses]
Eliminates sulfur from substituted thiophene complexes, leading to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole. | [Uses]
It eliminates sulfur from substituted thiophene complexes, which leads to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole. | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. | [Purification Methods]
It usually contains 10% by weight of MeOH as stabiliser. This can be removed by keeping it in a vacuum at 0.5mm for at least 5hours. It can be sublimed slowly at high vacuum and is soluble in organic solvents. [Landesberg et al. J Org Chem 37 930 1972, Case & Whiting J Chem Soc 4632 1960, King & Stone Inorg Synth VII 193 1963.] TOXIC. |
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