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18446-73-6

18446-73-6 Structure

18446-73-6 Structure
IdentificationBack Directory
[Name]

tembetarine
[CAS]

18446-73-6
[Synonyms]

tembetarine
(1S)-1,2,3,4-Tetrahydro-7-hydroxy-1-[(3-hydroxy-4-methoxyphenyl)methyl]-6-methoxy-2,2-dimethylisoquinolin-2-ium
[Molecular Formula]

C2oH2604N+
[MOL File]

18446-73-6.mol
Hazard InformationBack Directory
[Description]

A quaternary benzylisoquinoline alkaloid, this base is isolated as the crystalline chloride from the bark of Fagara naranjillo (Griseb.) Engl., m.p. 236-7°C; [α]29Db9 + 123.3° (c 0.9, EtOH). The salt gives an ultraviolet spectrum having a single absorption maximum at 284 ffi/J.. The dimethyl ether is identical with Laudano sine methyl ether and the diethyl ether forms a crystalline iodide, m.p. 91-2°C; [α]29Di>8 + 96.2° (c 0.85, CHCI 3).
[Definition]

ChEBI: (S)-tembetarine is a tembetarine obtained by methylation of the tertiary amino function of (R)-reticuline. It has a role as a plant metabolite. It is a benzylisoquinoline alkaloid and a tembetarine. It is functionally related to a (S)-reticuline. It is an enantiomer of a (R)-tembetarine.
[References]

Albonico, Kuck, Deulofeu., Chern. & Ind., 1580 (1964)
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