Identification | Back Directory | [Name]
1,2,3,4-Tetrahydro-6-methoxy-2-methyl-1-(2-methylpropyl)isoquinolin-7-ol | [CAS]
19485-63-3 | [Synonyms]
Lophocerine 1,2,3,4-Tetrahydro-6-methoxy-2-methyl-1-(2-methylpropyl)isoquinolin-7-ol | [Molecular Formula]
C15H23NO2 | [MOL File]
19485-63-3.mol | [Molecular Weight]
249.35 |
Hazard Information | Back Directory | [Description]
This alkaloid belongs to the isoquinoline group and is one of the cactus bases
being found in Lophocereus schottii. It is a colourless oil giving a crystalline
picrate and a styphnate with m.p. 191.5-193°C and 171-2°C respectively. The
structure has been established as 1:2:3:4-tetrahydro-7-hydroxy-l-isobutyl-6-
methoxy-2-methylisoquinoline. It yields a methyl ether, forming a picrate, m.p.
180-2°C and a styphnate, m.p. 210-2°C. The corresponding ethyl ether also
gives a picrate and styphnate with m.p. ISO-3°C and 182-3°C respectively. | [Definition]
ChEBI: Lophocerine is a member of isoquinolines. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 24, p. 1106, 1959 DOI: 10.1021/jo01090a018 | [References]
Bobbitt, Chou., J. Org. Chem., 24, 1106 (1959) |
|
|