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204933-84-6

204933-84-6 Structure

204933-84-6 Structure
IdentificationBack Directory
[Name]

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
[CAS]

204933-84-6
[Synonyms]

(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]
(S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]
[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
[NH2Me2][[RuCl((R)-H8-binap)]2(mu-Cl)3]
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II)
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II)
Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3] 
DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
[Molecular Formula]

2C44H40P2.C2H7N.Cl.Cl3Ru2.ClH
[MDL Number]

MFCD09753036
[MOL File]

204933-84-6.mol
[Molecular Weight]

1686.99
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

red-brown
[Sensitive ]

air sensitive
Questions And AnswerBack Directory
[Reaction]

  1. Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
  2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
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