| Identification | Back Directory | [Name]
Diethyl 2-((tosyloxy)imino)malonate | [CAS]
20893-05-4 | [Synonyms]
Diethyl 2-((tosyloxy)imino)malonate
Propanedioic acid, 2-[[[(4-methylphenyl)sulfonyl]oxy]imino]-, 1,3-diethyl ester | [Molecular Formula]
C14H17NO7S | [MDL Number]
MFCD31707687 | [MOL File]
20893-05-4.mol | [Molecular Weight]
343.35 |
| Hazard Information | Back Directory | [Uses]
As demonstrated by Laszlo Kürti′s lab, ketomalonate oxime O-sulfonates act as doubly N-electrophilic linchpin reagents towards strong C-nucleophiles such as alkyl- and arylmetals (e.g., Grignard reagents). Thus, symmetrical dialkyl- as well as diarylamines may be directly prepared at low tempretatures and in the absence of transition metal catalysts. Other ketomalonate oxime O-sulfonates include 902918, 902705 and 902748. |
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