ChemicalBook--->CAS DataBase List--->2153-26-6

2153-26-6

2153-26-6 Structure

2153-26-6 Structure
IdentificationBack Directory
[Name]

TERPINYL FORMATE
[CAS]

2153-26-6
[Synonyms]

FEMA 3052
TERPINYL FORMATE
ALPHA TERPINYL FORMATE
p-1-Menthen-8-ylformate
p-Menth-1-en-8-ylformiat
p-menth-1-en-8-ylformate
Formic acid p-menth-1-en-8-yl ester
Terpinyl formate, mixture of isomers
p-menth-1-en-8-ol,formate(mixedisomers)
TERPINYL FORMATE 97+% MIXTURE OF &
3-Cyclohexene-1-methanol, α,α,4-trimethyl-, 1-formate
alpha,alpha,4-trimethyl-3-cyclohexene-1-methanoformate
3-Cyclohexene-1-methanol,.alpha.,.alpha.-4-trimethyl-,formate
[EINECS(EC#)]

218-444-0
[Molecular Formula]

C11H18O2
[MDL Number]

MFCD00036672
[MOL File]

2153-26-6.mol
[Molecular Weight]

182.26
Chemical PropertiesBack Directory
[Boiling point ]

220 °C(lit.)
[density ]

0.981 g/mL at 25 °C(lit.)
[FEMA ]

3052 | TERPINYL FORMATE
[refractive index ]

n20/D 1.471(lit.)
[Fp ]

207 °F
[color ]

A colourless liquid.
[Odor]

at 100.00 %. floral lavender citrus fruity cypress herbal woody
[Odor Type]

floral
[JECFA Number]

367
[LogP]

3.26
[EPA Substance Registry System]

3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, formate (2153-26-6)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

2
[RTECS ]

OT0220000
[Toxicity]

Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1976).
Hazard InformationBack Directory
[Chemical Properties]

Terpinyl formate has a pleasant, floral, citrus odor with a bitter taste at high levels, becoming dry and fruity at lower levels.
[Occurrence]

Reported present in Ceylon cardamom essential oil.
[Uses]

Terpinyl formate finds some use in Citrus-colognes, in support of Neroli notes, Lavender-Bergamot-notes, green notes, etc. It is also used in certain topnote compositions with Citrus oils and "green" materials.
[Definition]

ChEBI: Alpha-Terpineol formate is a p-menthane monoterpenoid.
[Preparation]

By cold formylation of terpineol, using formic-acetic anhydride (Arctander, 1969). Uses: In public use before the 1920s. Use in fragrances in the USA amounts to approximately 10001b/yr.
[Synthesis]

May be produced from d-α-terpineol and formic acetic anhydride; the racemic α-terpineol is also obtained by an analogous synthesis.
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