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22236-45-9

22236-45-9 Structure

22236-45-9 Structure
IdentificationBack Directory
[Name]

S,S-DIMETHYL-N-(P-TOLUENESULFONYL)SULFOXIMINE
[CAS]

22236-45-9
[Synonyms]

Nsc202395
RARECHEM AQ A1 0067
n-(p-toluenesulfonyl)dimethylsulfoximine
N-(p-Toluenesulphonyl)dimethylsulphoximine
S,S-dimethyl-N-(p-tolylsulphonyl)sulphoximide
S,S-DIMETHYL-N-(P-TOLUENESULFONYL)SULFOXIMINE
S,S-DIMETHYL-N-(P-TOLUENESULPHONYL)SULPHOXIMINE
S,S-Dimethyl-N-(4-methylphenylsulfonyl)sulfoximide
S,S-Dimethyl-N-[(4-methylphenyl)sulfonyl]sulfoximide
Sulfoxime, S,S-dimethyl-N-[(4-methylphenyl)sulfonyl]-
[EINECS(EC#)]

244-861-2
[Molecular Formula]

C9H13NO3S2
[MDL Number]

MFCD00013922
[MOL File]

22236-45-9.mol
[Molecular Weight]

247.33
Chemical PropertiesBack Directory
[Melting point ]

167-169 °C(lit.)
[solubility ]

Soluble in EtOH, THF, DMSO.
[BRN ]

2119329
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

S,S-Dimethyl-N-(p-toluenesulfonyl)sulfoximine, is used as methylene-transfer agent. The anion adds to carbonyl compounds to give epoxides which can react with a further mole of reagent with ring expansion to give 2,2-disubstituted oxetanes. It is also used as a pharmaceutical intermediate.
Spectrum DetailBack Directory
[Spectrum Detail]

S,S-DIMETHYL-N-(P-TOLUENESULFONYL)SULFOXIMINE(22236-45-9)MS
S,S-DIMETHYL-N-(P-TOLUENESULFONYL)SULFOXIMINE(22236-45-9)1HNMR
S,S-DIMETHYL-N-(P-TOLUENESULFONYL)SULFOXIMINE(22236-45-9)IR1
S,S-DIMETHYL-N-(P-TOLUENESULFONYL)SULFOXIMINE(22236-45-9)IR2
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