ChemicalBook--->CAS DataBase List--->223259-63-0

223259-63-0

223259-63-0 Structure

223259-63-0 Structure
IdentificationBack Directory
[Name]

1,1'-SPIROBIINDANE-7,7'-DIOL
[CAS]

223259-63-0
[Synonyms]

SF120084
1,1'-SPIROBIINDANE-7,7'-DIOL
(S)-7,7'-Dihydroxy-1,1'-spirobiindane
S-2,2',3,3'-tetrahydro-1,1'-spirobi[indene]-7,7'-diol
S-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-di
1,1'-Spirobi[1H-indene]-7,7'-diol,2,2',3,3'-tetrahydro-
S-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol
(1S)-2,2',3,3'-tetrahydro-1,1'-Spirobi[1H-indene]-7,7'-diol
(S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[INDENE]-7,7'-DIOL, >=95%
1,1'-Spirobi[1H-indene]-7,7'-diol, 2,2',3,3'-tetrahydro-, (1S)-
(S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol, 99%e.e.
(S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diol, 98% (99% ee)
[Molecular Formula]

C17H16O2
[MDL Number]

MFCD16621090
[MOL File]

223259-63-0.mol
[Molecular Weight]

252.308
Chemical PropertiesBack Directory
[Melting point ]

155-156℃
[Boiling point ]

433.0±45.0 °C(Predicted)
[density ]

1.34±0.1 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

powder to crystaline
[pka]

9.70±0.20(Predicted)
[color ]

White to Orange to Green
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Magnesium sulfate-->Acetone-->n-Butyllithium-->Hydrogen peroxide-->Hydrogen-->Nickel-->Sodium bromide-->Methanesulfonic acid-->Boron tribromide-->3-Hydroxybenzaldehyde-->Cinchonidine-->3-Methoxybenzaldehyde-->Phosphotungstic acid hydrate
[Preparation Products]

(S)-1,1'-SPIROBIINDANE-7,7'-DIOL-->(R)-1,1'-SPIROBIINDANE-7,7'-DIOL
Safety DataBack Directory
[HS Code ]

2907.29.9000
Hazard InformationBack Directory
[Uses]

(S)-SPINOL is used to synthesis a new class of chiral phosphoric acids with spirobiindane as scaffold and employed to catalyze the asymmetric Friedel?Crafts reaction of indoles with imines to afford 3-indolyl methanamines.
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