| Identification | Back Directory | [Name]
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride | [CAS]
228120-95-4 | [Synonyms]
(S)-RuCl[(p-cymene)(T-BINAP)]Cl
[RuCl(p-cymene)((S)-tolbinap)]Cl
-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl | [Molecular Formula]
[C58H54ClP2Ru]+Cl− | [MDL Number]
MFCD09753014 | [MOL File]
228120-95-4.mol | [Molecular Weight]
982.97 |
| Chemical Properties | Back Directory | [Melting point ]
>100°C | [storage temp. ]
2-8°C | [Water Solubility ]
Insoluble in water | [form ]
solid | [color ]
yellow to dark brown | [Sensitive ]
air sensitive |
| Questions And Answer | Back Directory | [Reactions]
1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
2. Ligand for palladium-catalyzed α-arylation of ketones.
3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
5. Enantioselective conjugate reduction of lactones and lactams.
6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
7. Catalytic Aldol reaction to ketones.
8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
11. Rhodium-catalyzed cross cyclotrimerization.
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Energy Chemical
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http://www.energy-chemical.com |
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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