| Identification | Back Directory | [Name]
[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside | [CAS]
23544-46-9 | [Synonyms]
Ipalbine
4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside
[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside
β-D-Glucopyranoside, 4-[(8aS)-1,2,3,5,8,8a-hexahydro-7-methyl-6-indolizinyl]phenyl | [Molecular Formula]
C21H29NO6 | [MOL File]
23544-46-9.mol | [Molecular Weight]
391.46 |
| Hazard Information | Back Directory | [Description]
This alkaloid, which is the O-~-D-glucoside of ipalbidine, also occurs in Ipomoea
alba L. It is dextrorotatory with [α]23D + 32.5° (c 0.03, EtOH). The structure has
been confirmed by the total synthesis from 2-methoxypyrroline and the methyl
ester of acetylacetic acid. | [References]
Gourley et al., Chem. Commun., 709 (1969)
Total synthesis:
Wick, Bartlett, Dolphin., Helv. Chim. Acta., 54, 513 (1971) |
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