Identification | Back Directory | [Name]
(-)-Isopinocampheol | [CAS]
25465-65-0 | [Synonyms]
3-PINANOL (-)3-PINANOL (-)-pinan-3-ol Einecs 247-011-9 gcsumofenantiomers (-)-Isopinocampheol (-)-ISOPINOCAMPHEOL ISOPINOCAMPHEOL, (-)- (1R,2R,3R,5S)-3-PINANOL (1R,2R,3R,5S)-(-)-ISOPINOCAMPHEOL (1R,2R,3R,5S)-(-)-IsopinocaMpheol 98% 4,6,6-trimethyl-3-bicyclo[3.1.1]heptanol (-)-ISOPINOCAMPHEOL 97+% (GC SUM OF ENANTIOMERS) (1R,2R,3R,5S)-2,6,6-TRIMETHYL-BICYCLO[3.1.1]HEPTAN-3-OL Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1R,2R,3S,5S)-rel- (1R,2R,3R,5S)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol, (1R,2R,3R,5S)-3-Pinanol ()-Isopinocampheol,(1R,2R,3R,5S)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol, (1R,2R,3R,5S)-3-Pinanol (-)-Isopinocampheol, (1R,2R,3R,5S)-3-Pinanol, 3-Pinanol, (1R,2R,3R,5S)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol | [EINECS(EC#)]
247-011-9 | [Molecular Formula]
C10H18O | [MDL Number]
MFCD00064146 | [MOL File]
25465-65-0.mol | [Molecular Weight]
154.25 |
Chemical Properties | Back Directory | [Melting point ]
52-55 °C | [alpha ]
-34 º (c=20, EtOH) | [Boiling point ]
219 °C(lit.) | [density ]
0.8389 (rough estimate) | [refractive index ]
1.4710 (estimate) | [Fp ]
200 °F | [optical activity]
[α]22/D 34°, c = 20 in ethanol | [BRN ]
2038100 | [LogP]
2.720 (est) |
Hazard Information | Back Directory | [Purification Methods]
Dissolve it in Et2O, dry over MgSO4, filter, evaporate, then recrystallise it from pet ether. Also recrystallise it from aqueous EtOH and distil it in a vacuum. [Kergomard & Geneix Bull Soc Chim Fr 394 1958, Zweifel & Brown J Am Chem Soc 86 393 1964.] The 3,4-dinitrobenzoyl derivative has m 100-101o, the phenylcarbamoyl derivative has m 137-138o and the acid -phthalate has m 125-126o. [Beilstein 6 III 282, 283.] |
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