ChemicalBook--->CAS DataBase List--->261733-18-0

261733-18-0

261733-18-0 Structure

261733-18-0 Structure
IdentificationBack Directory
[Name]

4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
[CAS]

261733-18-0
[Synonyms]

NIXANTPHOS
N-XantPhos 97%
98% NixantPhos
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
4,6-Bis(diphenylphosphino)phenoxazine 97%
4,6-BIS(DIPHENYLPHOSPHINO)-10H-PHENOXAZINE
4,6-Bis(diphenylphosphino)phenoxazine, 98+%
4,6-Bis(diphenylphosphino)phenoxazine, min. 98%
4,6-Bis(diphenylphosphino)phenoxazine, NIXANTPHOS
4,6-Bis(diphenylphosphino)phenoxazine, 98+% NIXANTPHOS
4,6-Bis(diphenylphosphino)phenoxazine,min.98%NIXANTPHOS
[Molecular Formula]

C36H27NOP2
[MDL Number]

MFCD03788937
[MOL File]

261733-18-0.mol
[Molecular Weight]

551.55
Chemical PropertiesBack Directory
[Melting point ]

256-262 °C
[Boiling point ]

662.1±55.0 °C(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Powder
[pka]

1.34±0.20(Predicted)
[color ]

white to off-white
[Water Solubility ]

Miscible with water.
[InChIKey]

HSWZLYXRAOXOLL-UHFFFAOYSA-N
[CAS DataBase Reference]

261733-18-0
Hazard InformationBack Directory
[Uses]

4,6-Bis(Diphenylphosphino)phenoxazine is used as a palladium catalyst in reactions involving the synthesis of triarylmethanes.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

2934.99.4400
Questions And AnswerBack Directory
[Reactions]

  1. A large bite-angle chelating bisphosphine that provides high levels of linear-to-branched selectivity in the hydroformylation of alkenes.
  2. A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides.
Reactions of 261733-18-0
Spectrum DetailBack Directory
[Spectrum Detail]

4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE(261733-18-0)1HNMR
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE(261733-18-0)31PNMR
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