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26871-46-5

26871-46-5 Structure

26871-46-5 Structure
IdentificationBack Directory
[Name]

Isomahanimbine
[CAS]

26871-46-5
[Synonyms]

Isomahanimbin
Isomahanimbine
(-)-3,11-Dihydro-3,8-dimethyl-3-(4-methyl-3-penten-1-yl)-pyrano[3,2-a]carbazole
Pyrano[3,2-a]carbazole, 3,11-dihydro-3,8-dimethyl-3-(4-methyl-3-penten-1-yl)-, (-)-
[Molecular Formula]

C23H25NO
[MDL Number]

MFCD21333495
[MOL File]

26871-46-5.mol
[Molecular Weight]

331.45
Chemical PropertiesBack Directory
[Melting point ]

142°C
[solubility ]

Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
[form ]

Powder
Hazard InformationBack Directory
[Description]

The roots and leaves of Murraya koenigii Spreng. yield this alkaloid which is best crystallized from CH2 C1r hexane. It has [α]D - 6° (c 2.01, CHC1 3 ) and the ultraviolet spectrum in EtOH shows absorption maxima at 225, 278, 281, 295, 335 and 354 mp. Catalytic hydrogenation with Pd-C gives the tetrahydro deriva_x0002_tive, m.p. l66-7°C, as colourless crystals from pentane, the ultraviolet spectrum of which has absorption maxima at 220, 241, 255,260,306 and 320 mp. Treatment with methyl sulphate in NaOH yields the N-methyl compound, m.p. 94°C, giving an ultraviolet spectrum in EtOH consisting of absorption maxima at 240, 293,332,345 and 358 mp.
[Definition]

ChEBI: (+)-Mahanimbicine is a member of carbazoles.
[References]

Joshi, Kamat, Gawad., Tetrahedron, 26, 1475 (1970)
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