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26946-37-2

26946-37-2 Structure

26946-37-2 Structure
IdentificationBack Directory
[Name]

BARIUM PHOSPHITE
[CAS]

26946-37-2
[Synonyms]

BARIUM PHOSPHITE
Bariumphosphonat
barium phosphonate
[EINECS(EC#)]

248-126-7
[Molecular Formula]

BaHO3P
[MDL Number]

MFCD00046183
[MOL File]

26946-37-2.mol
[Molecular Weight]

217.31
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H332
[Precautionary statements ]

P261-P271-P304+P340-P312-P264-P270-P301+P312-P330-P501
Hazard InformationBack Directory
[Description]

Barium phosphite can have the molecular formula of BaHPO3 or Ba(H2PO3)2 with molecular weights of 216.3021 and 296.2739 g/mol, respectively. It is the latter that appears when a solution of phosphorous acid is reacted with the carbonate:
BaCO3 +H3PO3 ? Ba(H2PO3)2 +H2O + CO2
[Preparation]

Barium phosphite is soluble in water so that a vacuum evaporation is needed to form the hemihydrate, Ba(H2- PO3)2·0.5H2O. It can also be prepared by the action of ammonium phosphite on barium chloride:
BaCl2 (aq) + 2NH4HPO3 (aq) ? Ba(H2PO3)2·0.5H2O + 2NH4Cl (aq).
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