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287381-46-8

287381-46-8 Structure

287381-46-8 Structure
IdentificationBack Directory
[Name]

2 7-DI(TERT-BUTYL)-9-FLUORENYLMETHYL
[CAS]

287381-46-8
[Synonyms]

2 7-DI(TERT-BUTYL)-9-FLUORENYLMETHYL
2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate 97%
Carbonochloridic acid, [2,7-bis(1,1-diMethylethyl)-9H-fluoren-9-yl]Methyl ester
[Molecular Formula]

C23H27ClO2
[MDL Number]

MFCD03701519
[MOL File]

287381-46-8.mol
[Molecular Weight]

370.91
Chemical PropertiesBack Directory
[Melting point ]

66-70 °C(lit.)
[storage temp. ]

2-8°C
Safety DataBack Directory
[Symbol(GHS) ]


GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P280-P305+P351+P338-P310
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate may be used in the preparation of polymer-supported (2,7-di-tert-butyl-9-fluorenyl)methyl succinimidyl carbonate (Dtb-Fmoc-P-OSu), a polymeric reagent for protecting amino groups.
[General Description]

2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate contains 2,7-di-tert-butyl-Fmoc protecting group (Fmoc= fluorenylmethoxycarbonyl), which is more soluble in organic solvents when compared to its Fmoc analog. It can be prepared from fluorene in three steps, by di-tert-butylation, hydroxymethylation and phosgenation.
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