Identification | Back Directory | [Name]
T-BUTYLDIMETHYLSILANE | [CAS]
29681-57-0 | [Synonyms]
CFS-570 Co-Formula CFS-570 Butyldimethylsilane t-Butyldimethylsilyl T-BUTYLDIMETHYLSILANE triethyl-propyl-silane TERT-BUTYLDIMETHYLSILANE Dimethyl tert-butylsilane tert-ButyldiMethylsilane 95% (1,1-dimethylethyl)dimethyl- tert-Butyldimethylsilane > tert-Butyldimethylsilane Dimethyl(2-methyl-2-propanyl)silane Silane,(1,1-dimethylethyl)dimethyl- | [Molecular Formula]
C6H16Si | [MDL Number]
MFCD00010754 | [MOL File]
29681-57-0.mol | [Molecular Weight]
116.28 |
Chemical Properties | Back Directory | [Melting point ]
13°C | [Boiling point ]
81-83 °C(lit.)
| [density ]
0.701 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.4(lit.)
| [Fp ]
−9 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Specific Gravity]
0.701 | [Hydrolytic Sensitivity]
3: reacts with aqueous base | [BRN ]
2231162 | [InChIKey]
QCIWZIYBBNEPKB-UHFFFAOYSA-N | [CAS DataBase Reference]
29681-57-0 |
Hazard Information | Back Directory | [Uses]
Tert-Butyldimethylsilane (t-BuMe2SiH) is widely used for the protection of hydroxy groups in sugars. Its oxidation product, tert-butyldimethylsilyl hydroperoxide (t-BuMe2SiOOH), is used for preparing luminiscent sources and prostanoids, specifically clavulons[1].
| [References]
[1] D. S. Lutsik-Maksim. “Liquid-phase oxidation of tert-butyldimethylsilane.” Russian Journal of General Chemistry 74 10 (2004): 1508–1512.
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