| Identification | Back Directory | [Name]
Isoline | [CAS]
30000-36-3 | [Synonyms]
Isoline
Isoline【alkaloid】
(12S)-12-Acetoxy-15,20-dihydro-15β-hydroxysenecionan-11,16-dione
(12S,15S)-12-Acetoxy-15,20-dihydro-15-hydroxysenecionan-11,16-dione
[1,6]Dioxacyclododecino[2,3,4-gh]pyrrolizine-2,7-dione, 6-(acetyloxy)-3-ethyl-3,4,5,6,9,11,13,14,14a,14b-decahydro-3-hydroxy-5,6-dimethyl-, (3R,5R,6S,14aR,14bR)- | [Molecular Formula]
C20H29NO7 | [MDL Number]
MFCD22479210 | [MOL File]
30000-36-3.mol | [Molecular Weight]
395.45 |
| Hazard Information | Back Directory | [Description]
Senecio othonniformis yields this alkaloid which forms colourless crystals when
recrystallized from Me2CO-light petroleum. The alkaloid has [α]29D?? - 4.8°
(c 1.78, EtOH). Alkaline hydrolysis yields retronecine, acetic acid and isolinecic acid. Mass spectral data and chemical degradation studies have shown the latter
to be 2: 5-dihydroxy-3-methylheptane-2: 5-dicarboxylic acid or the 2 A-dihydroxy
isomer. | [References]
Gordon-Gray, Coucourakis.,J. Chern. Soc., C, 2312 (1970) |
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