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3345-29-7

3345-29-7 Structure

3345-29-7 Structure
IdentificationBack Directory
[Name]

2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene
[CAS]

3345-29-7
[Synonyms]

AC1L3BM1
PARYLENE HT
Parylene-AF4
2,2,3,3,8,8,9,9-Octa
parylene AF4(parylene HT)
2,2,3,3,8,8,9,9-octafluoro-
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene
Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 2,2,3,3,8,8,9,9-octafluoro-
TIANFU-CHEM CAS:3345-29-7 2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene
Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 2,2,3,3,8,8,9,9-octafluoro Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, octafluoro
[Molecular Formula]

C16H8F8
[MDL Number]

MFCD13194972
[MOL File]

3345-29-7.mol
[Molecular Weight]

352.22
Chemical PropertiesBack Directory
[Melting point ]

240-250°C
[Boiling point ]

259.3±40.0 °C(Predicted)
[density ]

1.47±0.1 g/cm3(Predicted)
[form ]

powder
[InChI]

InChI=1S/C16H8F8/c17-13(18)9-1-2-10(4-3-9)14(19,20)16(23,24)12-7-5-11(6-8-12)15(13,21)22/h1-8H
[InChIKey]

KCKIWSAAWFKXMA-UHFFFAOYSA-N
[SMILES]

C12C=CC(=CC=1)C(F)(F)C(F)(F)C1C=CC(=CC=1)C(F)(F)C2(F)F
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H413-H317
[Precautionary statements ]

P261-P272-P280-P302+P352-P333+P313-P321-P363-P501
Hazard InformationBack Directory
[Uses]

Parylen AF4 is extremely useful in high temperature applications and those in which long-term UV stability is required.
  • Aerospace
  • Military
  • Electronic
  • Medical
  • Industrial
  • Semiconductor (3D IC TSV electrical insulation , AMOLED De-bonding layer , Barrier layer )
  • Bio-MEMS electrode protection film
  • EWD (Electro Wetting Device) Liquid lens
[Application]

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane can be used:
(1) cross-coupling reactions. 4-iodo-1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane is successfully coupled to a variety of arylboronic acids and boronic acid pinacol esters with the exception of sterically-demanding systems such as mesityl. Using the standard Suzuki method, dicyclophane containing two octafluoro[2.2]paracyclophane units separated by one and two benzene rings can be prepared.
(2) Spectroscopic studies. It is an isomer of 1-fluorocyclopropane and has a shorter reaction time compared to 1-fluorocyclopropane. The spectral properties of this compound are similar to those of 1-fluorocyclopropane. Its mass spectrum shows peaks corresponding to molecular ions with m/e=256 and its fragmentation pattern corresponds to monosubstituted aromatic hydrocarbons.
[Preparation]

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane is synthesised using 1,4-Bis(bromodifluoromethyl)benzene as a raw material by chemical reaction.
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane synthesis
[General Description]

Characteristics of Parylen AF4 coating:
Specialties:
  • Unmatched UV stability
  • Excellent thermal stability at high service temperature (350)
  • Unmatched oxidation stability
  • Completely conformal coating
  • Superior crevice penetration, pin hole free
  • Anti-saline damage
  • Anti-stick ion

Barrier properties:
  • Chemical insolubility and solvent resistant
  • Low water absorption
  • Hydrophobic properties
  • Low gas permeability , no out-gassing

Physical & mechanical properties:
  • Transparent
  • Light-weight and ultra-thin
  • Low CTE
  • Low coefficient of friction
  • Good dry lubricity
  • Abrasion resistance
  • Stabilization of components and structures
  • Particulate immobilization

Electrical properties:
  • Electrical insulation
  • High dielectric strength
  • High volume resistivity ,ohm-cm
  • Low dissipation factor
  • Low dielectric constant
  • Mitigation of tin whisker growth

Biocompatibility and bio-stability
  • USP class VI
  • Microorganism resistance
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