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35789-01-6

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35789-01-6 Structure

35789-01-6 Structure
IdentificationBack Directory
[Name]

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
[CAS]

35789-01-6
[Synonyms]

)amide]samarium(III)
samarium tris(hexamethylsilazide)
samarium tris(hexamethyldisilazde)
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
tris(bis(trimethylsilyl)amino)samarium
Tris[N,N-bis(trimethylsilyl)amide]samarium
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III)
Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium
Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM
1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt
Tris[N,N-bis(trimethylsilyl)amide]samarium [[(CH3)3Si]2N]3Sm FW 631.51 M.p. 93-1060C
[Molecular Formula]

C18H54N3Si6Sm
[MDL Number]

MFCD03427097
[MOL File]

35789-01-6.mol
[Molecular Weight]

631.51
Chemical PropertiesBack Directory
[Melting point ]

93-106 °C(lit.)
[Boiling point ]

83-4°C/1x10-4mmHg
[Fp ]

36 °F
[form ]

solid
Safety DataBack Directory
[Symbol(GHS) ]


GHS02,GHS05
[Signal word ]

Danger
[Hazard statements ]

H228-H261-H314
[Precautionary statements ]

P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

F,C
[Risk Statements ]

11-14/15-34
[Safety Statements ]

16-26-36/37/39-43-45-7/8
[RIDADR ]

UN 3396 4.3/PG 2
[WGK Germany ]

3
[TSCA ]

No
Hazard InformationBack Directory
[Uses]

Reactant for synthesis of:
  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes

Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization
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