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40335-00-0

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40335-00-0 Structure

40335-00-0 Structure
IdentificationBack Directory
[Name]

2,4-diMethoxyquinoline
[CAS]

40335-00-0
[Synonyms]

Yu Borylation Ligand
2,4-diMethoxyquinoline
Quinoline, 2,4-dimethoxy-
[Molecular Formula]

C11H11NO2
[MOL File]

40335-00-0.mol
[Molecular Weight]

189.21
Chemical PropertiesBack Directory
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard InformationBack Directory
[Uses]

The Yu Borylation Ligand in tandem with bis(pinacolato)diboron (Aldrich 473294) under palladium catalysis can promote direct borylation of C(sp3)-H bonds. Yu and coworkers have displayed this on both alanine-derived amides and cyclopropanes with directing group assistance from the Yu-Wasa Auxiliary (Aldrich 791806).
[General Description]

Yu Borylation Ligand, also referred to as 2,4-dimethoxyquinoline, has been developed by Professor Jin-Quan Yu and coworkers. 2,4-dimethoxyquinoline can be prepared by reacting 2,4-dichloroquinoline with sodium methoxide.
Spectrum DetailBack Directory
[Spectrum Detail]

2,4-diMethoxyquinoline(40335-00-0)MS
2,4-diMethoxyquinoline(40335-00-0)IR1
2,4-diMethoxyquinoline(40335-00-0)IR2
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