Identification | Back Directory | [Name]
TRIMETHYLSILYL CHLOROSULFONATE | [CAS]
4353-77-9 | [Synonyms]
trimethylsilyl chlorosulphate TRIMETHYLSILYL CHLOROSULFONATE TRIMETHYLSILYLCHLOROSULPHONATE chlorosulfonate de trimethylsilyle Trimethyl(chlorosulfonyloxy)silane TriMethylsilyl chlorosulfonate 99% Chlorosulfonic acid trimethylsilyl ester Chlorosulfuric acid, trimethylsilyl ester [chlorosulfonyloxy(dimethyl)silyl]methane Chloridosulfuric acid trimethylsilyl ester Chlorosulfonic acid (trimethylsilyl) ester | [EINECS(EC#)]
224-425-8 | [Molecular Formula]
C3H9ClO3SSi | [MDL Number]
MFCD00040471 | [MOL File]
4353-77-9.mol | [Molecular Weight]
188.71 |
Chemical Properties | Back Directory | [Melting point ]
−26 °C(lit.) | [Boiling point ]
168-169 °C(lit.) | [density ]
1.225 g/mL at 25 °C(lit.) | [refractive index ]
n20/D 1.424(lit.) | [Fp ]
108 °F | [form ]
liquid | [Specific Gravity]
1.23 | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [BRN ]
1763675 |
Hazard Information | Back Directory | [Uses]
Trimethylsilyl chlorosulfonate may be used:
- in the sulfonation of small organic molecules
- in the synthesis of sulfonated polysulfone
- as sulfonating agent in the preparation of nano-structured organic-inorganic membranes for proton exchange membrane fuel cells (PEMFC) based on methacrylate and epoxy polymeric structures
- in the preparation of sulfonated polysulfone (sPS)/titanium dioxide (TiO2) composite membranes for use in PEMFCs
- in the preparation of iodosobenzene sulfate, required for the synthesis of cyclic sulfates
| [General Description]
Trimethylsilyl chlorosulfonate is commonly employed as sulfonating agent. |
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