Identification | Back Directory | [Name]
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE | [CAS]
470480-32-1 | [Synonyms]
(S,S,R,R)-TANGPHOS (S,S',R,R')-TANGPHOS (1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane 2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)- (1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS (1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS | [Molecular Formula]
C16H32P2 | [MDL Number]
MFCD06658118 | [MOL File]
470480-32-1.mol | [Molecular Weight]
286.37 |
Hazard Information | Back Directory | [Uses]
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Catalytic ligand used in:
- Preparation of α-borono-substituted alkylarenes by asymmetric hydroboration of styrenes catalyzed by copper(I)
- Enantioselective synthesis of spiroindane di-Me acetic acid via hydrogenation of spiroindane di-Me acetic acid catalyzed by Ru(II)
- Asymmetric γ-addition of thiols to allenoates
- Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
- Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles
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