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472-93-5

472-93-5 Structure

472-93-5 Structure
IdentificationBack Directory
[Name]

γ-Carotene
[CAS]

472-93-5
[Synonyms]

g-Carotene
Γ-CAROTENE
GAMMACAROTENE
gamma-Carotene >=90% (HPLC)
[Molecular Formula]

C40H56
[MDL Number]

MFCD29037199
[MOL File]

472-93-5.mol
[Molecular Weight]

536.89
Chemical PropertiesBack Directory
[Melting point ]

152-153.5°; mp 177.5°
[Boiling point ]

644.94°C (rough estimate)
[density ]

0.9380 (estimate)
[refractive index ]

1.5630 (estimate)
[storage temp. ]

-20°C
[solubility ]

Insoluble Diethyl ether
[form ]

solid
[λmax]

λ: 458-462 nm Amax
[BRN ]

3226412
Safety DataBack Directory
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

γ-Carotene may be used as a reference standard in the determination of γ-carotene in fruits using high performance liquid chromatography coupled with diode array detector (HPLC-DAD) and mass spectrometry (HPLC-MS).
[Definition]

ChEBI: A cyclic carotene obtained by the cyclisation of lycopene.
[General Description]

γ-Carotene is a plant carotenoid with provitamin A activity.
[Biochem/physiol Actions]

Metabolite in carotenoid biosynthesis and the biosynthesis of plant secondary metabolites.
[Purification Methods]

Purify γ-carotene by chromatography on alumina [Grade II in pet ether (b 60-80o) and elute with *C6H6], or magnesia columns. When crystallised from *C6H6/MeOH (2:1), it had m 177.5o. Store it in the dark, under an inert atmosphere at 0o, or in an evacuated tube at -20o. The purity is verified by TLC on Ca(OH)2/Kieselgel (8:2) using pet ether (b 60-80o) as eluant. [Manchand et al. J Chem Soc 2019 1965, Beilstein 5 III 2453, 5 IV 2617.]
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