ChemicalBook--->CAS DataBase List--->503538-70-3

503538-70-3

503538-70-3 Structure

503538-70-3 Structure
IdentificationBack Directory
[Name]

(R)-DIFLUORPHOS(TM)
[CAS]

503538-70-3
[Synonyms]

(S)-DIFLUORPHOS(TM)
(R)-DIFLUORPHOS(TM)
R-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE
S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97%
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloroMethane adduct (S)-DIFLUORPHOS
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole,dichloromethaneadduct,min.97%(S)-DIFLUORPHOS
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM)
[Molecular Formula]

C38H24F4O4P2
[MDL Number]

MFCD05861607
[MOL File]

503538-70-3.mol
[Molecular Weight]

682.54
Chemical PropertiesBack Directory
[Boiling point ]

670.9±55.0 °C(Predicted)
[form ]

Powder
[color ]

white
[Sensitive ]

air sensitive
[CAS DataBase Reference]

503538-70-3
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
Questions And AnswerBack Directory
[Reaction]

  1. Ligand used for the enantioselective hydrogenation of olefins, and especially electron-poor ketones.
  2. Ligand used for the enantioselective α-arylation of ketones.
  3. Ligand used for enantioselective alkylative aldol reactions.
  4. Nickel-catalyzed asymmetric α-heteroarylation of ketones with chloroarenes.
  5. Palladium-catalyzed asymmetric intramolecular arylation of α-keto amides.
Reactions of 503538-70-3
Hazard InformationBack Directory
[Uses]

(S)-DIFLUORPHOS is an electron-poor diphosphane, and can also be used as a chiral supporting ligand.Also, used in preparation of chiral Amino Acid Esters and deuterated Amino Acid Esters.
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