Identification | Back Directory | [Name]
1,1'-[(2,4-Diphenyl-1,3-cyclobutanediyl)dicarbonyl]bis[1,2,3,4-tetrahydro-5-(2-piperidinyl)pyridine] | [CAS]
528-31-4 | [Synonyms]
Santiaguine 1,1'-[(2,4-Diphenyl-1,3-cyclobutanediyl)dicarbonyl]bis[1,2,3,4-tetrahydro-5-(2-piperidinyl)pyridine] | [Molecular Formula]
C38H48N4O2 | [MOL File]
528-31-4.mol | [Molecular Weight]
592.81 |
Hazard Information | Back Directory | [Description]
A constituent of Adenocarpus intermedius, this alkaloid crystallizes from EtOH as colourless crystals. The base was originally given the reduced formula C19H240N2 and m.p. 235-6°C by Ribas and Talarid. It has [α]17D + 3.3° (c 0.368, EtOH) and forms a series of crystalline salts including the hydrochloride sesquihydrate, m.p. 238°C when crystallized from H20 and m.p. 241°C from EtOH; hydrobromide monohydrate, m.p. 244-253°C; hydriodide monohydrate, m.p. 241-2°C; perchlorate, m.p. 244-5°C (dec.); aurichloride, m.p. 150-l°C (dec.); platinichloride sesquihydrate, m.p. 226-7°C (dec.) and the picrate, m.p. 285°C. | [Definition]
ChEBI: (-)-Santiaguine is a tetrahydropyridine. | [References]
Ribas, Talarid., Mon. farm. y terap (Madrid), 56,377 (1950) Dominguez, Mendez, Ribas., Anales Real. Soc. Espan. Fis. Quim. (Madrid), 52B, 133 (1956) Biosynthesis: O'Donovan, Creedon., J. Chern. Soc., C, 1604 (1971) |
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