| Identification | Back Directory | [Name]
1,5-Methano-8H-pyrido(1,2-a)(1,4)diazocin-8-one, 3-(3-butenyl)-1,2,3,4 ,5,6-hexahydro-, (1R)- | [CAS]
529-78-2 | [Synonyms]
Rhombifolin
rhombifoline
(1R)-3-(3-Butenyl)-1,2,3,4,5,6-hexahydro-1α,5α-methano-8H-pyrido[1,2-a][1,5]diazocin-8-one
1,5-Methano-8H-pyrido(1,2-a)(1,4)diazocin-8-one, 3-(3-butenyl)-1,2,3,4 ,5,6-hexahydro-, (1R)-
1,5-Methano-8H-pyrido[1,2-a][1,5]diazocin-8-one, 3-(3-buten-1-yl)-1,2,3,4,5,6-hexahydro-, (1R,5S)- | [Molecular Formula]
C15H20N2O | [MDL Number]
MFCD34167512 | [MOL File]
529-78-2.mol | [Molecular Weight]
244.33 |
| Chemical Properties | Back Directory | [Boiling point ]
120 °C(Press: 0.2 Torr) | [density ]
1.14±0.1 g/cm3(Predicted) | [form ]
Liquid | [pka]
9.45±0.20(Predicted) | [color ]
Light yellow to light brown |
| Hazard Information | Back Directory | [Description]
A minor alkaloid obtained from Thermopsis rhombifolia (Watt), Richards, the
base was originally given the empirical formula ClsH2002N2, but subsequently
changed to that given. It is strongly laevorotatory with [α]25D - 232.4° (c 2.13,
EtOH) and yields crystalline salts including the hydrochloride, m.p. 256-8°C
(dec.) which sublimes at l20°CjO.000l mm; the perchlorate, m.p. 243-5°C (dec.);
platinichloride, m.p. 268° C and the picrate, m.p. 226°C (dec.). | [References]
Manske, Marion., Can. J. Res., 20B, 265 (1942)
Manske, Marion., ibid, 21B, 144 (1943)
Cockburn, Marion., Can. J. Chem., 30,92 (1952)
van Tamelen, Baran.,J. Amer. Chem. Soc., 71,4944 (1955) |
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