Identification | Back Directory | [Name]
(1R)-(-)-THIOCAMPHOR | [CAS]
53402-10-1 | [Synonyms]
(1R)-(-)-THIOCAMPHOR (1R)-(-)-Thiocamphor (1R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2-thione (1r)-(-)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-thione Bicyclo[2.2.1]heptane-2-thione, 1,7,7-trimethyl-, (1R,4R)- | [Molecular Formula]
C10H16S | [MDL Number]
MFCD00074855 | [MOL File]
53402-10-1.mol | [Molecular Weight]
168.3 |
Chemical Properties | Back Directory | [Melting point ]
136-138 °C(lit.)
| [Boiling point ]
228-230 °C(lit.)
| [density ]
0.9691 (rough estimate) | [refractive index ]
1.6500 (estimate) | [form ]
powder to crystal | [color ]
Light yellow to Brown |
Hazard Information | Back Directory | [Purification Methods]
It forms red prisms from EtOH and sublimes under vacuum. It possesses a sulfurous odour and is volatile like camphor. [Sen J Indian Chem Soc 12 647 1935, Sen J Indian Chem Soc 18 76 1941.] The racemate crystallises from *C6H6 and has m 145o [138.6-139o, White & Bishop J Am Chem Soc 62 10 1940]. [Beilstein 7 III 419.] |
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