| Identification | Back Directory | [Name]
TROPONE | [CAS]
539-80-0 | [Synonyms]
Tropon
TROPONE
Tropone,97%
Cycloheptatrienone
LABOTEST-BB LT00233179
2,4,6-CYCLOHEPTATRIENONE
cyclohepta-2,4,6-trienone
2,4,6-CYCLOHEPTATRIEN-1-ONE
2,4,6-Cycloheptatriene-1-one
cyclohepta-2,4,6-trien-1-one
2,4,6-Cyclo-heptatriene-1-one
2,4,6-CYCLOHEPTATRIEN-1-ONE 97%
Cycloheptane-2,4,6-triene-1-one | [EINECS(EC#)]
208-725-6 | [Molecular Formula]
C7H6O | [MDL Number]
MFCD00014331 | [MOL File]
539-80-0.mol | [Molecular Weight]
106.12 |
| Chemical Properties | Back Directory | [Melting point ]
-7°C | [Boiling point ]
113 °C15 mm Hg(lit.)
| [density ]
1.091 g/mL at 20 °C
| [refractive index ]
n20/D 1.615(lit.)
| [Fp ]
>110°C | [storage temp. ]
−20°C
| [form ]
Liquid | [color ]
very deep brown
| [BRN ]
1902335 |
| Hazard Information | Back Directory | [Uses]
Tropone has been used in synthesis of:
- bicyclic δ-lactones via heterocyclic carbine-catalyzed [8+3] annulation pathway
- 6,7-benzobicyclo [3.2.2] nona-3,6,8-trien-2-one via thermal addition to bezyne
| [Synthesis Reference(s)]
Journal of the American Chemical Society, 78, p. 5442, 1956 DOI: 10.1021/ja01601a077
The Journal of Organic Chemistry, 29, p. 960, 1964
Organic Syntheses, Coll. Vol. 9, p. 396, 1998 | [General Description]
Metal-catalyzed [6+3] cycloaddition of tropone with azomethine ylides has been reported. |
|
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Alfa Aesar
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Energy Chemical
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Sigma-Aldrich
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