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5460-63-9

5460-63-9 Structure

5460-63-9 Structure
IdentificationBack Directory
[Name]

methyl(±)cis,trans-2,2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate)
[CAS]

5460-63-9
[Synonyms]

Nsc23735
Methyl chrysanthemate
methyl (dl)-trans-chrysanthemate
2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid methyl ester
Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, methyl ester
3-(2-Methyl-1-propenyl)-2,2-dimethylcyclopropane-1-carboxylic acid methyl ester
2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylic acid methyl ester
methyl(±)cis,trans-2,2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate)
methyl(±)cis,trans-2,2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate)
Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, methyl ester
[Molecular Formula]

C11H18O2
[MDL Number]

MFCD02093821
[MOL File]

5460-63-9.mol
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Dimethyl sulfoxide-->Copper-->Hydroquinone-->Sodium formate-->Methyl acetate-->3-Methyl-1-butene-->Methyl 3-methyl-2-butenoate-->BENZENESULFINIC ACID SODIUM SALT-->diazoacetic acid-->2,5-Dimethyl-2,4-hexadiene-->1-Chloro-3-methyl-2-butene
[Preparation Products]

(1R-cis)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropane carboxylic acid-->Ethyl chrysanthemumate-->1R-trans-methyl caronaldehydate
Hazard InformationBack Directory
[Chemical Properties]

A pale yellow or colorless oily liquid. Insoluble in water, soluble in ethanol, methanol, benzene, acetone and other organic solvents.
[Uses]

Methyl chrysanthemum is an important intermediate of pyrethroids, which can be used to synthesize allethrin, promethrin, permethrin, dimethrin, metothrin, pyrethrin, and fenothrin.
[Synthesis]

Methyl chrysanthemate was synthesized by reacting 2,5-dimethyl-2,4-hexadiene with methyl diazoacetate solution in prestence of a catalyst.
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