ChemicalBook--->CAS DataBase List--->57345-19-4

57345-19-4

57345-19-4 Structure

57345-19-4 Structure
IdentificationBack Directory
[Name]

dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin
[CAS]

57345-19-4
[Synonyms]

amber oxepin
AMBER KETAL IPM
Einecs 260-686-4
KETAMBER 10 P. IN APV
dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin
5H-3,5a-Epoxynaphth[2,1-c]oxepin, dodecahydro-3,8,8,11a-tetramethyl-
5,5,9,13-Tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane
5,5,9,13-Tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane
1,2,3,6,7,7a,8,9,10,11,11a,11b-Dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin
[EINECS(EC#)]

260-686-4
[Molecular Formula]

C18H30O2
[MOL File]

57345-19-4.mol
[Molecular Weight]

278.43
Chemical PropertiesBack Directory
[Boiling point ]

300.9±10.0 °C(Predicted)
[density ]

1.05±0.1 g/cm3(Predicted)
[vapor pressure ]

0.001Pa at 20℃
[form ]

Solid:bulk
[Odor]

at 10.00 % in dipropylene glycol. dry amber powdery woody musk
[Odor Type]

amber
[LogP]

5.9 at 30℃ and pH7
[EPA Substance Registry System]

5H-3,5a-Epoxynaphth[2,1-c]oxepin, dodecahydro-3,8,8,11a-tetramethyl- (57345-19-4)
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H413-H315
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362
Hazard InformationBack Directory
[Chemical Properties]

Dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin is a colorless to pale yellow liquid. It possesses a powerful amber note with good stability in nonaggressive media.
[Preparation]

The synthesis starts from the natural raw material manool, which is obtained by extraction from a tree growing in New Zealand, the so-called pink pine, Halocarpus biformis (Hooker) C.J. Quinn. Epoxidation of manool, subsequent oxidative degradation of the allylalcohol side chain to yield a ketone, and intramolecular acetalization afford the ketal.
[Trade name]

Ambermore Ketal (Aromor), Amberketal (Givaudan), Z11 (Firmenich).
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