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5794-03-6

5794-03-6 Structure

5794-03-6 Structure
IdentificationBack Directory
[Name]

(+)-CAMPHENE
[CAS]

5794-03-6
[Synonyms]

C06304
FEMA 2229
d-Camphene
Camphene, (1R,4S)-(+)-
(+)-CAMPHENE 80+% FCC
(+)-CAMPHENE, TECH., 80%
(+)-CAMPHENE ISO 9001:2015 REACH
(+)-Camphene technical grade, 80%
2,2-Dimethyl-3-methylenenorborhane
(1R,4S)-2,2-dimethyl-3-methylene-norbornane
2,2-dimethyl-3-methylene-,(1R)-Bicyclo[2.2.1]heptane
2-dimethyl-3-methylene-(1theta)-bicyclo[2.2.1]heptan
(1α,4α)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
(1β,4β)-2-Methylene-3,3-dimethylbicyclo[2.2.1]heptane
(1R,4S)-6,6-dimethyl-5-methylidenebicyclo[2.2.1]heptane
(1S,4R)-3,3-dimethyl-2-methylidenebicyclo[2.2.1]heptane
(1R,4S)-6,6-dimethyl-5-methylidene-bicyclo[2.2.1]heptane
Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1R,4S)-
[1R,4S,(+)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
(+)-Camphene,(1R)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
[EINECS(EC#)]

227-336-2
[Molecular Formula]

C10H16
[MDL Number]

MFCD00003756
[MOL File]

5794-03-6.mol
[Molecular Weight]

136.23
Chemical PropertiesBack Directory
[Melting point ]

40-50 °C(lit.)
[Boiling point ]

159-160 °C(lit.)
[density ]

0.839 g/mL at 25 °C(lit.)
[refractive index ]

1.4562 (estimate)
[Fp ]

98 °F
[solubility ]

Benzene (Slightly), Chloroform (Slightly),
[form ]

Solid
[color ]

White to Off-White Waxy
[Odor]

at 10.00 % in dipropylene glycol. fresh herbal woody fir camphor
[Odor Type]

woody
[optical activity]

[α]20/D +16°, c = 4 in ethanol
[LogP]

4.220
[EPA Substance Registry System]

Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1R,4S)- (5794-03-6)
Safety DataBack Directory
[Hazard Codes ]

F
[Risk Statements ]

11
[Safety Statements ]

16-33
[RIDADR ]

UN 1325 4.1/PG 2
[WGK Germany ]

3
Hazard InformationBack Directory
[Physical properties]

Camphene is a colorless, crumbly crystalline solid with a camphor-like odor. It has a tendency to sublime.
[Uses]

(+)-Camphene is part of a mixture which is responsible for the anti-inflammatory effect of essential oil from Citrus aurantium L. var. amara Engl.
[Definition]

ChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has R configuration at position 1 and S configuration at position 4.
[Production Methods]

The extraction of camphene by distillation of turpentine is now hardly used in industry. Instead camphene is produced from a-pinene.
[Chemical Reactivity]

Camphene is stable in air and light. At elevated temperatures, in the presence of oxygen, it undergoes autoxidation to camphenilone. Peracids attack the double bond, giving camphene oxide. Catalytic hydrogenation gives the saturated hydrocarbon isocamphane.
[Biochem/physiol Actions]

Taste at 100 ppm
Spectrum DetailBack Directory
[Spectrum Detail]

(+)-CAMPHENE(5794-03-6)1HNMR
(+)-CAMPHENE(5794-03-6)IR
(+)-CAMPHENE(5794-03-6)Raman
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