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5794-04-7

5794-04-7 Structure

5794-04-7 Structure
IdentificationBack Directory
[Name]

(-)-CAMPHENE
[CAS]

5794-04-7
[Synonyms]

L-Camphene
(-)-Camphene
(-)-Camphene,95%
(1S,4R)-2,2-Dimethyl-3-methylenenorbornane
(+/-)-Camphene, sum of camphene + fenchene
2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
(1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE
2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane
(1R,4S)-3,3-Dimethyl-2-methylenebicyclo[2.2.1]heptane
Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-
[1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
()-Camphene,(1S)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
[EINECS(EC#)]

227-337-8
[Molecular Formula]

C10H16
[MDL Number]

MFCD00064161
[MOL File]

5794-04-7.mol
[Molecular Weight]

136.23
Chemical PropertiesBack Directory
[Melting point ]

36-38 °C(lit.)
[Boiling point ]

157.5-158.5 °C(lit.)
[density ]

0.84 g/mL at 25 °C(lit.)
[refractive index ]

1.4562 (estimate)
[Fp ]

98 °F
[solubility ]

Benzene (Slightly), Chloroform (Sparingly)
[form ]

Solid
[color ]

White to Off-White Waxy
[Odor]

at 10.00 % in dipropylene glycol. fresh woody fir terpene
[Odor Type]

woody
[Merck ]

14,1730
[Stability:]

Volatile
[LogP]

4.239 (est)
[EPA Substance Registry System]

Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1S,4R)- (5794-04-7)
Safety DataBack Directory
[Hazard Codes ]

F
[Risk Statements ]

11-10
[Safety Statements ]

16-33-29
[RIDADR ]

UN 1325 4.1/PG 2
[WGK Germany ]

3
[RTECS ]

EX1055000
[HazardClass ]

4.1
[PackingGroup ]

III
Hazard InformationBack Directory
[Uses]

(-)-Camphene has been observed in the chemical composition of essential oils from different morphological parts of Pinus cembra L.
[Definition]

ChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has S configuration at position 1 and R configuration at position 4.
[Purification Methods]

Purify norbornane by fractionation through a Stedman column (see p. 11) at 100mm in a N2 atmosphere, crystallise it from EtOH and sublime it in a vacuum below its melting point. It is characterised by its camphenilone semicarbazone, m 217-218.5o, or camphor semicarbazone, m 236-238o. [NMR: Hana & Koch Chem Ber 111 2527 1978, Bartlett et al. Justus Liebigs Ann Chem 623 217 1959, Bain et al. J Am Chem Soc 72 3124 1950, Beilstein 5 IV 461.]
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