| Identification | Back Directory | [Name]
1-BROMO-1-PROPENE | [CAS]
590-14-7 | [Synonyms]
1-bromo-propen
1-Bromopropene
1-Brom-1-propen
1-bromo-1-propen
PROPENYL BROMIDE
1-bromopropylene
1-Propenylbromid
Propene, 1-bromo-
1-BROMO-1-PROPENE
1-PROPENYL BROMIDE
1-bromo-prop-1-ene
1-Propene,1-bromo-
1-Propene, 1-bromo-
(1E)-1-Bromo-1-propene
1-Bromo-1-propene
TRANS-1-BROMO-1-PROPENE
1-Bromo-1-propene,cis+trans
Propenyl bromide (cis-trans)
1-Bromo-1-propene (cis+trans)
1-bromo-1-propene (cis and trans)
1-bromo-1-propene,mixtureofisomers
1-Bromo-1-Propene,MixtureOfIsomers98%
1-Bromo-1-propene,mixtureofcisandtrans
1-Bromo-1-propene (cis- and trans- mixture)
1-BROMO-1-PROPENE, 98%, MIXTURE OF ISOME RS
1-Bromo-1-propene, mixture of cis and trans,98%
1-Bromo-1-propene (cis and trans),1-Propenyl bromide
1-Bromo-1-propene, 95%, mixture of isomers, stabilized
1-Bromo-1-propene, mixture of isomers, stabilized, 95%
1-Bromo-1-propene (cis- and trans- mixture)
1-BroMo-1-propene, Mixture of isoMers, stabilized, 95% 5ML | [EINECS(EC#)]
209-671-6 | [Molecular Formula]
C3H5Br | [MDL Number]
MFCD00000186 | [MOL File]
590-14-7.mol | [Molecular Weight]
120.98 |
| Chemical Properties | Back Directory | [Appearance]
clear colourless to yellow liquid | [Melting point ]
−116 °C(lit.)
| [Boiling point ]
64-65 °C(lit.)
| [density ]
1.420 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.454
| [Fp ]
5 °F
| [storage temp. ]
2-8°C
| [form ]
clear liquid | [color ]
Colorless to Light yellow to Light orange | [BRN ]
1719096 | [CAS DataBase Reference]
590-14-7 | [EPA Substance Registry System]
1-Propene, 1-bromo- (590-14-7) |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID | [Uses]
1-Bromo-1-propene upon n-BuLi treatment generates the propynyllithium anion, in situ, which later undergoes nucleophilic addition reactions. Some of its other applications are:
- Synthesis of organic reagents such as methyl but-2-ynoate and 1-iodopropyne.
- Preparation o f intermediates in the total synthesis of (+)-aphanamol I and skyllamycins A-C.
- Synthesis of allylated pyrazoles, aryl alkynyl sulfides and allenamides.
| [Uses]
1-Propenyl bromide is a useful building block, especially when a 3 carbon addition is required, such as its use in the synthesis of the pharmaceutical spilanthol. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 56, p. 4066, 1991 DOI: 10.1021/jo00012a053 |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|