Identification | Back Directory | [Name]
LATIFOLINE | [CAS]
6029-86-3 | [Synonyms]
LATIFOLINE (2R)-Tetrahydro-3β-hydroxy-2α,4α-dimethyl-5-oxofuran-3-carboxylic acid [[(7R,7aR)-5,6,7,7a-tetrahydro-7-[(Z)-2-methyl-2-butenoyloxy]-3H-pyrrolizin]-1-yl]methyl ester 3-Furancarboxylic acid, tetrahydro-3-hydroxy-2,4-dimethyl-5-oxo-, [(1R,7aR)-2,3,5,7a-tetrahydro-1-[[(2Z)-2-methyl-1-oxo-2-butenyl]oxy]-1H-pyrrolizin-7-yl]methyl ester, (2R,3S,4S)- (9CI) | [Molecular Formula]
C20H27NO7 | [MOL File]
6029-86-3.mol | [Molecular Weight]
393.43 |
Hazard Information | Back Directory | [Description]
An alkaloid extracted from the bark of Funturnia latifolia Stapf., this base
crystallizes from MeOH, m.p. 162-6°C and from Me2CO with m.p. 129°C. The
natural base is laevorotatory with [α]D- 4.0° (c 0.8, CHCI 3 ), the synthetic
optically inactive form having m.p. 170.5-171.5° C. A crystalline acetyl derivative has been prepared, m.p. 160°C; [α]D - 15° (c 1.2, CHCI 3 ). The structure
has been shown from spectroscopic evidence to be 5-conanen-3~-01. | [Definition]
ChEBI: Latifoline is a carbonyl compound. | [References]
Janot, Khuong Huu, Goutarel., Cornpt. rend., 254, 1326 (1962)
Nagata, Terasawa, Aoki., Tetrahedron Lett., 869 (1963) |
|
|