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608-73-1

608-73-1 Structure

608-73-1 Structure
IdentificationBack Directory
[Name]

BHC
[CAS]

608-73-1
[Synonyms]

dol
BHC
HCH
fbhc
gyben
kotol
gamtox
isatox
submar
dolmix
benzex
hexafor
hexamul
hexylan
BHC-Mix
trives-t
BHC Tech
latka666
bhcorhch
ent8,601
benzahex
benzanex
gamaspra
gammacide
gammacoid
hexablanc
hexachlor
ambiocide
soprocide
hexapoudre
technicalbhc
technicalhch
compound-666
mixedisomers
hch (bsi,iso)
bhc (iso,jmaf)
HCH-MIXEDISOMERS
TECHNICAL-GRADEHCH
BHC (MIXED ISOMERS)
HCH (TOTAL ISOMERS)
BENZENE HEXACHLORIDE
HCH (BHC), Technical
hexachlorocyclohexanes
lindane(bhcorhch-mixedisomers)
BHC (MIXED ISOMERS), 1GM, NEAT
benzenehexachloride,mixedisomers
1,2,3,4,5,6-hexachloro-cyclohexan
hexachlorocyclohexane(allisomers)
Cyclohexane,1,2,3,4,5,6-hexachlor
BHC (mixed isomers) 1g [608-73-1]
hexachlorocyclohexane(mixedisomers)
Hexachlorocyclohexane, isomer mixture
bhc (mixture of hexachlorocyclohexanes)
BHC (BENZENE HEXACHLORIDE), 500MG, NEAT
HCH MIXTURE OF ISOMERS (ALPHA+BETA+GAMMA
HCH ( BHC) ( technical), 100 μg/mL in methanol
1,2,3,4,5,6-hexachloro-cyclohexan(mixedisomers)
1,2,3,4,5,6-hexachlorocyclohexane(mixtureofisomers)
Hexachlorocyclohexane (mixed isomers) Technical grade
[EINECS(EC#)]

210-168-9
[Molecular Formula]

C6H6Cl6
[MDL Number]

MFCD00003825
[MOL File]

608-73-1.mol
[Molecular Weight]

290.83
Chemical PropertiesBack Directory
[Definition]

An environmentally persistent constituent of a wide variety of agricultural, medical, and veterinary products.
[Appearance]

BHC is a white-to-brownish crystalline solid with a musty, phosgene-like odor.
[form ]

Powder or Flakes
[Uses]

Insecticide.
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

21-25-40-50/53-64-48/22-20/21
[Safety Statements ]

22-36/37-45-60-61
[RIDADR ]

2761
[RTECS ]

GV4375000
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by ingestion and skin contact. Poison by ingestion, skin contact, and subcutaneous routes. Human systemic effects by inhalation: headache, nausea or vomiting, and fever. Implicated in aplastic anemia. Experimental reproductive effects. Mutation data reported. Lindane is more toxic than DDT or dieldrin. Potentially violent reaction with dlmethylformamide + iron. When heated to decomposition it emits highly toxic fumes of phosgene, HCl, and Cl-. See other benzenehexachloride entries. A toxic organochlorine that is persistent in the environment and accumulates in mammalian tissue. For cattle, the oral LD50 <= 100 mg/kg. The various isomers have dlfferent actions; the y (lindane) and a isomers are central nervous system stimulants, the principal symptom being convulsions. The p and A isomers are central nervous system depressants. The use of thermal vaporizers with lindane has caused acute poisoning by inhalation. mixture has been estimated at about 30 g and the dangerous dose of lindane at about 7 to 15 g. However, as already mentioned, a single dose of 45 mg (or approximately 0.65 mg/kg) of lindane caused convulsions. Lindane shows a marked dfference in toxicity to dfferent species. Its toxic effect on laboratory animals compares favorably with that of DDT, but for several domestic animals, notably calves, hdane is more toxic than DDT or Qeldrin. On a chronic systemic basis the a, p and y isomers are experimental carcinogens. Has been implicated in aplastic anemia. Dermatitis and perhaps other manifestations based on sensitivity represent a sort of chronic, though probably not systemic intoxication, which has been observed in humans. The signs and symptoms of confirmed acute poisoning in humans have paralleled those in experimental animals. These signs and symptoms are: excitation, hyperirritability, loss of equhbrium, clonictonic convulsions, and later depression.There is some evidence that the pulmonary edema and vascular collapse may be of neurogenic origm also. The symptoms in animals systemically poisoned by the yisomer alone are essentially similar to those caused by mixtures, although the onset may be earlier. Workers acutely exposed to high air concentrations of lindane and its decomposition products show headache, nausea, and irritation of eyes, nose, and throat. In rare instances, urticaria has followed exposure to lindane vapor. Unlike the signs and symptoms already mentioned, this allergic manifestation occurs only in susceptible individuals, and usually only after a period of sensitization.
Hazard InformationBack Directory
[General Description]

White to yellow powder or flakes. Musty odor. The gamma isomer is known as lindane, a systemic insecticide. Toxic by ingestion or inhalation.
[Reactivity Profile]

Halogenated aliphatic compounds, such as HEXACHLOROCYCLOHEXANE, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
[Hazard]

Highly toxic; questionable carcinogen.
[Potential Exposure]

The major commercial usage of BHC is based upon its insecticidal properties. α-BCH is used as an Agricultural chemical, pesticide, pharmaceutical, and veterinary drug. The 7-isomer has the highest acute toxic ity, but the other isomers are not without activity. It is gen erally advantageous to purify the 7-isomer from the less active isomers. The γ-isomer acts on the nervous system of insects, principally at the level of the nerve ganglia. As a result, lindane has been used against insects in a wide range of applications including treatment of animals, buildings, humans for ectoparasites, clothes; water for mosquitoes; living plants; seeds and soils. Some applications have been abandoned due to excessive residues, e.g., stored food stuffs. By voluntary action, the principal domestic producer of technical grade BHC requested cancellation of its BHC registrations on September 1, 1976. As of July 21, 1978, all registrants of pesticide products containing BHC voluntar ily canceled their registrations or switched their former BHC products to lindane formulations.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 30 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Speed in removing material from skin is of extreme importance. Shampoo hair promptly if con taminated. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi cal attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Decomposes on contact with powdered iron, aluminum, zinc, and on contact with strong bases producing trichlorobenzene.
[Waste Disposal]

A process has been developed for the destructive pyrolysis of benzene hexachloride @ 400 500℃ with a catalyst mixture which contains 5 10% of either cupric chloride, ferric chloride; zinc chloride; or aluminum chloride on activated carbon.
Spectrum DetailBack Directory
[Spectrum Detail]

BHC(608-73-1)MS
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