| Identification | Back Directory | [Name]
1-(DIETHOXYMETHYL)IMIDAZOLE | [CAS]
61278-81-7 | [Synonyms]
1-(DIETHOXYMETHYL)IMIDAZOLE
1-(diethoxymethyl)-1H-imidazole
1H-Imidazole, 1-(diethoxymethyl)-
1-(Diethoxymethyl)imidazole >=97.0% | [Molecular Formula]
C8H14N2O2 | [MDL Number]
MFCD00956331 | [MOL File]
61278-81-7.mol | [Molecular Weight]
170.21 |
| Chemical Properties | Back Directory | [Boiling point ]
52 °C(Press: 0.02 Torr) | [density ]
1.041 g/mL at 20 °C (lit.) | [refractive index ]
n20/D 1.464 | [Fp ]
112℃ | [storage temp. ]
2-8°C | [form ]
liquid | [pka]
6.13±0.20(Predicted) | [BRN ]
908482 |
| Hazard Information | Back Directory | [Uses]
1-(Diethoxymethyl)imidazole may be used in the preparation of various hydroxy- and amino-functionalized imidazoles, via isoprene-mediated lithiation followed by reaction with an electrophile. | [General Description]
1-(Diethoxymethyl)imidazole is an orthoamide protected imidazole. The dianion reacts selectively at the 2 position 1-(Diethoxymethyl)imidazole is a 1-substituted imidazoles. Isoprene-mediated lithiation of 1-(diethoxymethyl)imidazole, leads to the preparation of the corresponding 2-lithio intermediate, which reacts with different electrophiles to afford 2-functionalised imidazoles. |
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